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Rubidium–strontium dating - Wikipedia
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The slope of the line dictates the age of the sample. Several preconditions must be satisfied before a Rb-Sr date can be considered as representing the time of emplacement or formation of a rock. One of the major drawbacks and, conversely, the most important use of utilizing Rb and Sr to derive a radiometric date is their relative mobility, especially in hydrothermal fluids. Rb and Sr are relatively mobile alkaline elements and as such are relatively easily moved around by the hot, often carbonated hydrothermal fluids present during metamorphism or magmatism.
Conversely, these fluids may metasomatically alter a rock, introducing new Rb and Sr into the rock generally during potassic alteration or calcic albitisation alteration.
Rb-Sr can then be used on the altered mineralogy to date the time of this alteration, but not the date at which the rock formed. Thus, assigning age significance to a result requires studying the metasomatic and thermal history of the rock, any metamorphic events, and any evidence of fluid movement. A Rb-Sr date which is at variance with other geochronometers may not be useless, it may be providing data on an event which is not representing the age of formation of the rock.
The Rb-Sr dating method has been used extensively in dating terrestrial and lunar rocks, and meteorites. The dates indicate the true age of the minerals only if the rocks have not been subsequently altered. Although this is a potential source of error for terrestrial rocks, it is irrelevant for lunar rocks and meteorites, as there are no chemical weathering reactions in those environments.
The application of Sr isotope stratigraphy is generally limited to carbonate samples for which the Sr seawater curve is well defined. This is well known for the Cenozoic time-scale but, due to poorer preservation of carbonate sequences in the Mesozoic and earlier, it is not completely understood for older sequences.
Sometimes, however, numerous discordant dates from the same rock will plot along a line representing a chord on the Concordia diagram. Such a chord is called a discordia. We can also define what are called Pb-Pb Isochrons by combining the two isochron equations 7 and 8.
Since we know that the , and assuming that the Pb and Pb dates are the same, then equation 11 is the equation for a family of lines that have a slope. The answer is about 6 billion years. This argument tells when the elements were formed that make up the Earth, but does not really give us the age of the Earth. It does, however, give a maximum age of the Earth. Is this the age of the Earth? Lunar rocks also lie on the Geochron, at least suggesting that the moon formed at the same time as meteorites. Modern Oceanic Pb - i.
Pb separated from continents and thus from average crust also plots on the Geochron, and thus suggests that the Earth formed at the same time as the meteorites and moon. Thus, our best estimate of the age of the Earth is 4. The initial ratio has particular importance for studying the chemical evolution of the Earth's mantle and crust, as we discussed in the section on igneous rocks.
Since K is one of the 10 most abundant elements in the Earth's crust, the decay of 40 K is important in dating rocks. But this scheme is not used because 40 Ca can be present as both radiogenic and non-radiogenic Ca. Since Ar is a noble gas, it can escape from a magma or liquid easily, and it is thus assumed that no 40 Ar is present initially. Note that this is not always true. If a magma cools quickly on the surface of the Earth, some of the Ar may be trapped. If this happens, then the date obtained will be older than the date at which the magma erupted.
For example lavas dated by K-Ar that are historic in age, usually show 1 to 2 my old ages due to trapped Ar.
Such trapped Ar is not problematical when the age of the rock is in hundreds of millions of years. The dating equation used for K-Ar is: Some of the problems associated with K-Ar dating are Excess argon. This is only a problem when dating very young rocks or in dating whole rocks instead of mineral separates.
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Minerals should not contain any excess Ar because Ar should not enter the crystal structure of a mineral when it crystallizes. Thus, it always better to date minerals that have high K contents, such as sanidine or biotite. If these are not present, Plagioclase or hornblende. If none of these are present, then the only alternative is to date whole rocks. Some 40 Ar could be absorbed onto the sample surface. This can be corrected for. Most minerals will lose Ar on heating above o C - thus metamorphism can cause a loss of Ar or a partial loss of Ar which will reset the atomic clock. If only partial loss of Ar occurs then the age determined will be in between the age of crystallization and the age of metamorphism.
If complete loss of Ar occurs during metamorphism, then the date is that of the metamorphic event.
The problem is that there is no way of knowing whether or not partial or complete loss of Ar has occurred. Examples of questions on this material that could be asked on an exam. Prior to the best and most accepted age of the Earth was that proposed by Lord Kelvin based on the amount of time necessary for the Earth to cool to its present temperature from a completely liquid state. Principles of Radiometric Dating Radioactive decay is described in terms of the probability that a constituent particle of the nucleus of an atom will escape through the potential Energy barrier which bonds them to the nucleus.
Thus, if we start out with 1 gram of the parent isotope, after the passage of 1 half-life there will be 0. Some examples of isotope systems used to date geologic materials.
To see how we actually use this information to date rocks, consider the following: To account for this, we first note that there is an isotope of Sr, 86 Sr, that is: